Krivácsy, ZoltánHoffer, AndrásSárvári, ZsoltTemesi, DóraBaltensperger, UrsNyeki, StephanWeingartner, ErnestKleefeld, SilkeJennings, Stephen Gerard2024-08-192024-08-192001-101352-23100004-698110.1016/s1352-2310(01)00467-8https://irf.fhnw.ch/handle/11654/46843The mass concentrations of inorganic ions, water-soluble organic carbon, water-insoluble organic carbon and black carbon were determined in atmospheric aerosol collected at three European background sites: (i) the Jungfraujoch, Switzerland (high-alpine, PM2.5 aerosol); (ii) K-puszta, Hungary (rural, PM1.0 aerosol); (iii) Mace Head, Ireland (marine, total particulate matter). At the Jungfraujoch and K-puszta the contribution of carbonaceous compounds to the aerosol mass was higher than that of inorganic ions by 33% and 94%, respectively. At these continental sites about 60% of the organic carbon was water soluble, 55–75% of the total carbon proved to be refractory and a considerable portion of the water soluble, refractory organic matter was composed of humic-like substances. At Mace Head the mass concentration of organic matter was found to be about twice than that of nonsea-salt ions, 40% of the organic carbon was water soluble and the amount of highly refractory carbon was low. Humic-like substances were not detected but instead low molecular weight carboxylic acids were responsible for about one-fifth of the water-soluble organic mass. These results imply that the influence of carbonaceous compounds on aerosol properties (e.g. hygroscopic, optical) might be significant.en550 - GeowissenschaftenRole of organic and black carbon in the chemical composition of atmospheric aerosol at European background sites01A - Beitrag in wissenschaftlicher Zeitschrift6231-6244