A novel route to molecular self-assembly. Self-intermixed monolayer phases

de Wild, MichaelBerner, SimonSuzuki, HitoshiYanagi, HisaoSchlettwein, DerckIvan, StanislavBaratoff, AlexisGuentherodt, Hans-JoachimJung, Thomas A.2024-05-132024-05-132002-10-181439-42351439-764110.1002/1439-7641(20021018)3:10<881::AID-CPHC881>3.0.CO;2-Phttps://irf.fhnw.ch/handle/11654/45799The stars and stripes: A novel route to highly perfect molecular self-assembly is presented. Depending on the relative surface (Ag(111)) coverage of the two species, subphthalocyanine and C60 (green and yellow in the colored STM image) on an surface, well-ordered intermixed monolayers consisting of 1D chains with 1 nm width or 2D hexagonal patterns are formed. The structural parameters and schematic binary "phase diagram" of this system are deduced from detailed room-temperature STM studies. The most important underlying interactions and the relevant properties of the molecules are discussed qualitatively.enIntermixing; MonolayersNanostructuresScanning probe microscopySelf-assembly600 - Technik, Medizin, angewandte WissenschaftenA novel route to molecular self-assembly. Self-intermixed monolayer phases01A - Beitrag in wissenschaftlicher Zeitschrift881-885