Phosphorus recovery in an acidic environment using layer-by-layer modified membranes

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Autor:in (Körperschaft)
Publikationsdatum
15.07.2019
Typ der Arbeit
Studiengang
Typ
01A - Beitrag in wissenschaftlicher Zeitschrift
Herausgeber:innen
Herausgeber:in (Körperschaft)
Betreuer:in
Übergeordnetes Werk
Journal of Membrane Science
Themenheft
Reihe / Serie
Reihennummer
Jahrgang / Band
582
Ausgabe / Nummer
Seiten / Dauer
254-263
Patentnummer
Verlag / Herausgebende Institution
Elsevier
Verlagsort / Veranstaltungsort
Auflage
Version
Programmiersprache
Abtretungsempfänger:in
Praxispartner:in/Auftraggeber:in
Zusammenfassung
Phosphorus (P) is a limited natural resource and essential for global food supply, particularly given our ever-growing world population. However, natural P deposits are restricted to just a few countries and the quality of exploited primary sources is declining. Phosphorus recovery from sewage sludge or sewage sludge ash leached by acids is hence gaining importance. During P recovery the removal of impurities is a challenge that can be addressed by nanofiltration retaining e. g. multivalent metals and allowing phosphoric acid to pass. However, currently available membranes show low permeability and limit this process option economically. Layer-by-layer (LbL) membrane synthesis is a technology that allows membrane performance to be tailored to individual filtration tasks. Little is known for such membranes with respect to acid resistance, acid permeability and impurity rejection. We show that LBL membranes based on PDADMAC/PSS show the desired passage of phosphoric acid with retentions values below 10%, aluminum retention was always above 95%. Permeabilities up to 4 L/(m2 h bar) were reached even up to a phosphorous recovery of 75%. Overall permeabilities were 16 times higher than a commercial benchmark membrane. Initial stability tests and upscaling into a larger module show the viability of the proposed modification approach.
Schlagwörter
LbL modified membranes, Acidic application, P recovery, Nanofiltration, Sewage sludge ash
Fachgebiet (DDC)
Projekt
Veranstaltung
Startdatum der Ausstellung
Enddatum der Ausstellung
Startdatum der Konferenz
Enddatum der Konferenz
Datum der letzten Prüfung
ISBN
ISSN
1873-3123
0376-7388
Sprache
Englisch
Während FHNW Zugehörigkeit erstellt
Ja
Publikationsstatus
Veröffentlicht
Begutachtung
Peer-Review der ganzen Publikation
Open Access-Status
Lizenz
Zitation
REMMEN, Kirsten, Barbara MÜLLER, Joachim KÖSER und Thomas WINTGENS, 2019. Phosphorus recovery in an acidic environment using layer-by-layer modified membranes. Journal of Membrane Science. 15 Juli 2019. Bd. 582, S. 254–263. DOI 10.1016/j.memsci.2019.03.023. Verfügbar unter: https://irf.fhnw.ch/handle/11654/30645