Two-dimensional calix[4]arene-based metal-organic coordination networks of tunable crystallinity

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Authors
Moradi, Mina
Nowakowski, Jan
Jung, Thomas A
Baljozovic, Milos
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Publication date
13.11.2017
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01A - Journal article
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Angewandte Chemie: International Edition
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Volume
56
Issue / Number
46
Pages / Duration
14395–14399
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Publisher / Publishing institution
Wiley
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Abstract
A flexible and versatile method to fabricate two-dimensional metal–organic coordination networks (MOCNs) by bottom-up self-assembly is described. 2D crystalline layers were formed at the air–water interface, coordinated by ions from the liquid phase, and transferred onto a solid substrate with their crystallinity preserved. By using an inherently three-dimensional amphiphile, namely 25,26,27,28-tetrapropoxycalix[4]arene-5,11,17,23-tetracarboxylic acid, and a copper metal node, large and monocrystalline dendritic MOCN domains were formed. The method described allows for the fabrication of monolayers of tunable crystallinity on liquid and solid substrates. It can be applied to a large range of differently functionalized organic building blocks, also beyond macrocycles, which can be interconnected by diverse metal nodes.
Keywords
two-dimensional, calix[4]arene-based metal-organic, tunable crystallinity
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1521-3773
1433-7851
0570-0833
Language
English
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Yes
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Published
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Peer review of the complete publication
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Citation
MORADI, Mina, Ludovico TULLI, Jan NOWAKOWSKI, Thomas A JUNG, Patrick SHAHGALDIAN und Milos BALJOZOVIC, 2017. Two-dimensional calix[4]arene-based metal-organic coordination networks of tunable crystallinity. Angewandte Chemie: International Edition. 13 November 2017. Bd. 56, Nr. 46, S. 14395–14399. DOI 10.1002/anie.201703825. Verfügbar unter: http://hdl.handle.net/11654/25899