Corvini, Philippe

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Corvini
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Philippe
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Corvini, Philippe

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2012 - 20166
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Autor:in: Lenz, Markus × Enddatum: 2016 ×

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Gerade angezeigt 1 - 6 von 6
  • Vorschaubild nicht verfügbar
    Publikation
    Environmental aspects of printable and organic electronics (POE)
    (Pan Stanford Publishing, 04/2016) Hengevoss, Dirk; Zimmermann, Yannick; Brun, Nadja; Hugi, Christoph; Lenz, Markus; Corvini, Philippe; Fent, Karl; Nisato, Giovanni; Lupo, Donald; Ganz, Simone [in: Organic and Printed Electronics: Fundamentals and Applications]
    04A - Beitrag Sammelband
  • Vorschaubild nicht verfügbar
    Publikation
    Arsenic Mobilization from Historically Contaminated Mining Soils in a Continuously Operated Bioreactor: Implications for Risk Assessment
    (Taylor & Francis, 2016) Rajpert, Liwia; Kolvenbach, Boris; Ammann, Erik; Hockmann, Kerstin; Nachtegaal, Maarten; Eiche, Elisabeth; Schäffer, Andreas; Corvini, Philippe; Sklodowska, Aleksandra; Lenz, Markus [in: Environmental Science & Technology]
    Concentrations of soil arsenic (As) in the vicinity of the former Złoty Stok gold mine (Lower Silesia, southwest Poland) exceed 1000 μg g–1 in the area, posing an inherent threat to neighboring bodies of water. This study investigated continuous As mobilization under reducing conditions for more than 3 months. In particular, the capacity of autochthonic microflora that live on natural organic matter as the sole carbon/electron source for mobilizing As was assessed. A biphasic mobilization of As was observed. In the first two months, As mobilization was mainly conferred by Mn dissolution despite the prevalence of Fe (0.1 wt % vs 5.4 for Mn and Fe, respectively) as indicated by multiple regression analysis. Thereafter, the sudden increase in aqueous As[III] (up to 2400 μg L–1) was attributed to an almost quintupling of the autochthonic dissimilatory As-reducing community (quantitative polymerase chain reaction). The aqueous speciation influenced by microbial activity led to a reduction of solid phase As species (X-ray absorption fine structure spectroscopy) and a change in the elemental composition of As hotspots (micro X-ray fluorescence mapping). The depletion of most natural dissolved organic matter and the fact that an extensive mobilization of As[III] occurred after two months raises concerns about the long-term stability of historically As-contaminated sites.
    01A - Beitrag in wissenschaftlicher Zeitschrift
  • Vorschaubild nicht verfügbar
    Publikation
    Immobilization of an artificial imine reductase within silica nanoparticles improves its performance
    (Royal Society of Chemistry, 2016) Hestericová, Martina; Correro, Maria Rita; Lenz, Markus; Corvini, Philippe; Shahgaldian, Patrick; Ward, Thomas R. [in: Chemical Communications]
    Silica nanoparticles equipped with an artificial imine reductase (biotinylated iridium complex conjugated with streptavidin) display marked redn. activity toward cyclic imines and NAD. The method, based on immobilization and protection of streptavidin on silica nanoparticles, shields the biotinylated metal cofactor against deactivation yielding >46,​000 turnovers in pure samples and 4000 turnovers in crude cellular exts.
    01A - Beitrag in wissenschaftlicher Zeitschrift
  • Vorschaubild nicht verfügbar
    Publikation
    Biomineralisierung von Selen: Von Abwasserbehandlung zu Ressourcen-Wiedergewinnung
    (2015) Lenz, Markus; Kolvenbach, Boris; Corvini, Philippe
    06 - Präsentation
  • Vorschaubild nicht verfügbar
    Publikation
    Are degrading OPV materials still sustainable?
    (2015) Zimmermann, Yannick; Brun, Nadja; Hengevoss, Dirk; Corvini, Philippe; Fent, Karl; Hugi, Christoph; Lenz, Markus
    06 - Präsentation
  • Vorschaubild nicht verfügbar
    Publikation
    Organic photovoltaics: Potential fate and effects in the environment
    (Elsevier, 2012) Zimmermann, Yannick-Serge; Schäffer, Andreas; Hugi, Christoph; Fent, Karl; Corvini, Philippe; Lenz, Markus [in: Environment International]
    In times of dwindling fossil fuels it is particularly crucial to develop novel “green” technologies in order to cover the increasing worldwide demand for energy. Organic photovoltaic solar cells (OPVs) are promising as a renewable energy source due to low energy requirement for production, low resource extraction, and no emission of greenhouse gasses during use. In contrast to silicium-based solar cells, OPVs offer the advantages of light-weight, semi-transparency and mechanical flexibility. As to a possible forthcoming large-scale production, the environmental impact of such OPVs should be assessed and compared to currently best available technologies. For the first time, this review compiles the existing knowledge and identifies gaps regarding the environmental impact of such OPVs in a systematic manner. In this regard, we discuss the components of a typical OPV layer by layer. We discuss the probability of enhanced release of OPV-borne components into the environment during use-phase (e.g. UV- and biodegradation) and end-of-life phase (e.g. incineration and waste disposal). For this purpose, we compiled available data on bioavailability, bioaccumulation, biodegradation, and ecotoxicity. Whereas considerable research has already been carried out concerning the ecotoxicity of certain OPV components (e.g. nanoparticles and fullerenes), others have not been investigated at all so far. In conclusion, there is a general lack of information about fate, behavior as well as potential ecotoxicity of most of the main OPV components and their degradation/transformation products. So far, there is no evidence for a worrying threat coming from OPVs, but since at present, no policy and procedures regarding recycling of OPVs are in action, in particular improper disposal upon end-of-life might result in an adverse effect of OPVs in the environment when applied in large-scale.
    01A - Beitrag in wissenschaftlicher Zeitschrift