Corvini, Philippe
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Philippe
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Corvini, Philippe
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- PublikationThe sulfonamide-resistance dihydropteroate synthase gene is crucial for efficient biodegradation of sulfamethoxazole by Paenarthrobacter species(Springer, 13.07.2023) Wu, Tong; Guo, Sheng-Zhi; Zhu, Hai-Zhen; Yan, Lei; Liu, Zhi-Pei; Li, De-Feng; Jiang, Cheng-Ying; Corvini, Philippe; Shen, Xi-Hui; Liu, Shuang-Jiang [in: Applied Microbiology and Biotechnology]01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationEfficient catalytic ozonation over Co-ZFO@Mn-CN for oxalic acid degradation. Synergistic effect of oxygen vacancies and HOO-Mn-NX bonds(Elsevier, 03/2023) Xu, Menglu; Zhang, Yibing; Yin, Huaqin; Wang, Jinnan; Li, Aimin; Corvini, Philippe [in: Applied Catalysis B: Environmental]01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationBoosting light harvesting and charge separation over hollow double-shelled Ag@SrTiO3-TiO2 with Z-scheme heterostructure for highly efficient photocatalytic reduction of nitrate to N2(Elsevier, 01.02.2023) Zhang, Yixuan; Liu, Cong; Zhou, Ye; Wang, Jinnan; Li, Aimin; Corvini, Philippe [in: Chemical Engineering Journal]01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationHierarchical nano-vesicles with bimetal-encapsulated for peroxymonosulfate activation. Singlet oxygen-dominated oxidation process(Elsevier, 01.04.2022) Lyu, Zhiping; Xu, Menglu; Wang, Jinnan; Li, Aimin; Corvini, Philippe [in: Chemical Engineering Journal]Hierarchical nano-vesicles with bimetal-encapsulated (FeCu1.5O3@NV) was designed for peroxymonosulfate (PMS) activation with the 1O2-dominated oxidation process. Different from previous core–shell metal-loaded catalysts, FeCu1.5O3 was encapsulated in hollow zeolite spheres, and these zeolite sphere units assembled to construct hierarchical nano-vesicles. Owning to mesoporous shell and abundant interior cavity, FeCu1.5O3@NV could enrich reactants in cavity for enhancing the contact with active sites. The flexible surface of bimetal oxides strengthened the affinity with surface adsorbates and substrates, accelerating the electron transfer between reactants. DFT calculation indicated that FeCu1.5O3@NV possessed strong binding affinity for BPA and PMS, facilitating PMS activation and BPA degradation inside of hollow sphere units. Being attributed to the synergistic effect of bimetal redox couples and hierarchical nano-vesicle structure, large amounts of 1O2 could be generated through two pathways for BPA degradation. The first pathway is the reaction between bimetal redox couples and PMS, and the second is the chain reaction of O2•−. Due to bimetal oxides uniformly encapsulated in hierarchical nano-vesicles, FeCu1.5O3@NV possessed high catalytic stability with negligible metal leaching. Even after 5 cycles, BPA removal could still remain 100%.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationBiOBr/ Bi4O5Br2/PDI constructed for visible-light degradation of endocrine disrupting chemicals. Synergistic effects of bi-heterojunction and oxygen evolution(Elsevier, 01.04.2022) Wang, Haoyi; Zhou, Ye; Wang, Jinnan; Li, Aimin; Corvini, Philippe [in: Chemical Engineering Journal]To remove endocrine disrupting chemicals (EDCs), visible-light response photocatalyst BiOBr/Bi4O5Br2/perylene diimide (PDI) with bi-heterojunction was constructed. Under visible-light irradiation, BiOBr/Bi4O5Br2/PDI could degrade 90% Bisphenol A (BPA) within 75 min, while degrade 100% 17α-ethynyl estradiol (EE2) and 17β-estradiol (E2) within 15 min. Radicals quenching experiment and EPR indicated both •O2– and holes were the main substances for EDCs degradation, and the possible degradation pathway of EDCs are proposed based on the LC-MS analysis results. In the composite of BiOBr/Bi4O5Br2/PDI, the matching energy band structure between Bi4O5Br2 and BiOBr facilitated the formation of heterojunction for strengthening the space charge separation. Meanwhile, PDI with strong photosensitivity combined with BiOBr/Bi4O5Br2 not only enhanced visible-light photocatalytic activity but also broadened the light-harvesting range. Owning to the unique one-dimensional conjugated structure and internal electric field effect, PDI could also promote the photo-carriers transfer and separation. With the bi-heterojunction effect, photo-generated electrons were transferred to BiOBr conduction band while holes were accumulated on PDI valence band. Simultaneously, holes could oxidize water with the production of oxygen following being reduced to •O2– by photo-generated electrons. Even under oxygen-poor conditions, the production of •O2– can reach 32.7 × 10-5mol•g−1•h−1, resulting in more than 85% BPA degradation within 75 min.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationUltrafine-Mn2O3@N-doped porous carbon hybrids derived from Mn-MOFs: Dual-reaction centre catalyst with singlet oxygen-dominant oxidation process(Elsevier, 2022) Xie, Zhiqun; Lyu, Zhiping; Wang, Jinnan; Li, Aimin; Corvini, Philippe [in: Chemical Engineering Journal]Ultrafine-Mn2O3@N-doped porous carbon hybrids [Mn2O3@NC] derived from Mn-MOFs was constructed with 1O2 and O2−• as main Reactive oxygen species (ROS). Cation-π bonds and N-Mn complexation induced the formation of electron-rich Mn centre which provided electron for peroxymonosulfate activation to produce radicals, accompanying with generation of 1O2 via chain reaction. Notably, the porous structure of N-doped carbon shell could not only facilitate free radical recombination for generation of 1O2 but also provide adsorption sites for organics. On the other hand, as electron-poor centre, N-doped carbon shell could improve the electrons transfer from organic intermediate radicals to electron-rich Mn centre via π -π reaction, C-O-Mn and C-N-Mn bonds, which promote the redox of Mn to avoid peroxymonosulfate invalid decomposition. Being attributed to synergistic effects of dual-reaction centres and strong oxidation ability of 1O2, Mn2O3@NC achieved high mineralization of BPA at low-dose peroxymonosulfate (0.033 g/L).01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationEngineering efficient hole transport layer Ferrihydrite-MXene on BiVO4 photoanodes for photoelectrochemical water splitting: Work function and conductivity regulated(Elsevier, 2022) Bai, Weihao; Zhou, Ye; Peng, Gang; Wang, Jinnan; Li, Aimin; Corvini, Philippe [in: Applied Catalysis B: Environmental]Although great interest is focused on development of semiconductor photoanodes for efficient photoelectrochemical (PEC) water splitting, the pressing bottleneck to address the intrinsic charge transport for enhancement of PEC performance still remains to be resolved. Herein, hole transport layer (Fh-MXene) constructed by doping of MXene (Ti3C2) in Ferrihydrite (Fh) is loaded on BiVO4 photoanode. This novel BiVO4@Fh-MXene photoanode achieves high current density of 4.55 mA cm−2 at 1.23 V versus reversible hydrogen electrode (vs. RHE), exhibiting excellent photostability. From electrochemical analysis and density functional theory calculations, high PEC performance is ascribed to incorporation of Fh-MXene as hole transport layer, enhancing conductivity and water oxidation reaction. Notably, MXene can improve band alignment of BiVO4/Fh-MXene interface by tuning work function, which strengthens the built-in electric field for more efficient hole extraction. This work provides a simple method to design photoanodes with efficient charge transport layers for feasible PEC water splitting application.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationSpecial issue in memory of Valter Tandoi (IRSA-CNR) - A life-long commitment to environmental biotechnology(Elsevier, 25.05.2021) Rosetti, Simona; Corvini, Philippe; Majone, Mauro [in: New Biotechnology]01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationLong-term field study on fate, transformation, and vertical transport of tetrabromobisphenol A in soil–plant systems(American Chemical Society, 21.03.2021) Corvini, Philippe; Songfeng, Wang; Xuan, Wu; Rong, Guo; Wang, Qilin; Guo, Hongyan; Sun, Feifei; Ji, Rong [in: Environmental Science & Technology]Soil contamination with tetrabromobisphenol A (TBBPA) has been an environmental concern for many years, but in situ studies of the fate and potential risk of TBBPA are lacking. In this study, we investigated the dissipation, metabolism, strong alkali-hydrolytic (SAH-TBBPA), and vertical movement of TBBPA in the field with and without rice-wheat rotation and reed growth for 1225 days. After 342 days of incubation, 21.3% of the TBBPA remained in the surface soil accompanied by obvious leaching to deeper soil layers in the first 92 days. By day 1225, TBBPA was nearly absent from the surface soil layer. A very low amount of SAH-TBBPA (2.31–3.43 mg/kg) was detected during the first 342 days of incubation. In the surface soil, five metabolites were identified that represented four interconnected pathways: oxidative skeletal cleavage, O-methylation, type II ipso-substitution, and reductive debromination. Both rice–wheat rotation and monocultural reed growth accelerated TBBPA removal in the field by stimulating the anaerobic debromination and aerobic O-methylation, especially the oxidative skeletal cleavage of TBBPA in the rhizosphere soil. Though far from comprehensive, our study investigated the natural attenuation and metabolism of TBBPA in situ and the influence by crops to estimate the environmental risk of TBBPA in a field scale.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationMicrobial interactions drive the complete catabolism of the antibiotic sulfamethoxazole in activated sludge microbiomes(American Chemical Society, 02.03.2021) Corvini, Philippe; Qi, Mengyuan; Liang, Bin; Ma, Xiaodan; Yan, Lei; Dong, Wenchen; Kong, Deyong; Zhang, Liying; Zhu, Haizhen; Gao, Shu-Hong; Jiang, Jiandong; Liu, Shuan-Jiang; Wang, Aijie [in: Environmental Science & Technology]Microbial communities are believed to outperform monocultures in the complete catabolism of organic pollutants via reduced metabolic burden and increased robustness to environmental challenges; however, the interaction mechanism in functional microbiomes remains poorly understood. Here, three functionally differentiated activated sludge microbiomes (S1: complete catabolism of sulfamethoxazole (SMX); S2: complete catabolism of the phenyl part of SMX ([phenyl]-SMX) with stable accumulation of its heterocyclic product 3-amino-5-methylisoxazole (3A5MI); A: complete catabolism of 3A5MI rather than [phenyl]-SMX) were enriched. Combining time-series cultivation-independent microbial community analysis, DNA-stable isotope probing, molecular ecological network analysis, and cultivation-dependent function verification, we identified key players involved in the SMX degradation process. Paenarthrobacter and Nocardioides were primary degraders for the initial cleavage of the sulfonamide functional group (-C-S-N- bond) and 3A5MI degradation, respectively. Complete catabolism of SMX was achieved by their cross-feeding. The co-culture of Nocardioides, Acidovorax, and Sphingobium demonstrated that the nondegraders Acidovorax and Sphingobium were involved in the enhancement of 3A5MI degradation. Moreover, we unraveled the internal labor division patterns and connections among the active members centered on the two primary degraders. Overall, the proposed methodology is promisingly applicable and would help generate mechanistic, predictive, and operational understanding of the collaborative biodegradation of various contaminants. This study provides useful information for synthetic activated sludge microbiomes with optimized environmental functions.01A - Beitrag in wissenschaftlicher Zeitschrift