Two-dimensional calix[4]arene-based metal-organic coordination networks of tunable crystallinity

dc.accessRightsAnonymous
dc.audienceScience
dc.contributor.authorMoradi, Mina
dc.contributor.authorTulli, Ludovico
dc.contributor.authorNowakowski, Jan
dc.contributor.authorJung, Thomas A
dc.contributor.authorShahgaldian, Patrick
dc.contributor.authorBaljozovic, Milos
dc.date.accessioned2018-01-23T08:45:02Z
dc.date.available2018-01-23T08:45:02Z
dc.date.issued2017-11-13
dc.description.abstractA flexible and versatile method to fabricate two-dimensional metal–organic coordination networks (MOCNs) by bottom-up self-assembly is described. 2D crystalline layers were formed at the air–water interface, coordinated by ions from the liquid phase, and transferred onto a solid substrate with their crystallinity preserved. By using an inherently three-dimensional amphiphile, namely 25,26,27,28-tetrapropoxycalix[4]arene-5,11,17,23-tetracarboxylic acid, and a copper metal node, large and monocrystalline dendritic MOCN domains were formed. The method described allows for the fabrication of monolayers of tunable crystallinity on liquid and solid substrates. It can be applied to a large range of differently functionalized organic building blocks, also beyond macrocycles, which can be interconnected by diverse metal nodes.
dc.identifier.doi10.1002/anie.201703825
dc.identifier.issn1521-3773
dc.identifier.issn1433-7851
dc.identifier.issn0570-0833
dc.identifier.urihttp://hdl.handle.net/11654/25899
dc.issue46
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofAngewandte Chemie: International Editionen_US
dc.subjecttwo-dimensional
dc.subjectcalix[4]arene-based metal-organic
dc.subjecttunable crystallinity
dc.titleTwo-dimensional calix[4]arene-based metal-organic coordination networks of tunable crystallinity
dc.type01A - Beitrag in wissenschaftlicher Zeitschrift
dc.volume56
dspace.entity.typePublication
fhnw.InventedHereYes
fhnw.IsStudentsWorkno
fhnw.PublishedSwitzerlandNo
fhnw.ReviewTypeAnonymous ex ante peer review of a complete publication
fhnw.affiliation.hochschuleHochschule für Life Sciencesde_CH
fhnw.affiliation.institutInstitut für Chemie und Bioanalytikde_CH
fhnw.pagination14395–14399
fhnw.publicationOnlineJa
fhnw.publicationStatePublished
relation.isAuthorOfPublicationf780b314-13b7-4f19-b00b-a343db80c02e
relation.isAuthorOfPublication8884cd16-817b-4fba-a564-50a45970baa2
relation.isAuthorOfPublication.latestForDiscoveryf780b314-13b7-4f19-b00b-a343db80c02e
Dateien