Influence of gas-to-particle partitioning on the hygroscopic and droplet activation behaviour of α-pinene secondary organic aerosol
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Autor:innen
Jurányi, Zsófia
Gysel, Martin
Duplissy, Jonathan
Tritscher, Torsten
Dommen, Josef
Henning, Silvia
Ziese, Markus
Kiselev, Alexej
Stratmann, Frank
Autor:in (Körperschaft)
Publikationsdatum
05.08.2009
Typ der Arbeit
Studiengang
Typ
01A - Beitrag in wissenschaftlicher Zeitschrift
Herausgeber:innen
Herausgeber:in (Körperschaft)
Betreuer:in
Übergeordnetes Werk
Physical Chemistry Chemical Physics
Themenheft
DOI der Originalpublikation
Link
Reihe / Serie
Reihennummer
Jahrgang / Band
11
Ausgabe / Nummer
36
Seiten / Dauer
8091-8097
Patentnummer
Verlag / Herausgebende Institution
Royal Society of Chemistry
Verlagsort / Veranstaltungsort
London
Auflage
Version
Programmiersprache
Abtretungsempfänger:in
Praxispartner:in/Auftraggeber:in
Zusammenfassung
Hygroscopic properties of secondary organic aerosol (SOA) formed by photooxidation of different concentrations (10–27 or 220–270 ppb) of α-pinene precursor were investigated at different relative humidities (RH) using a hygroscopicity tandem differential mobility analyzer (HTDMA, RH = 95–97%) and using the mobile version of the Leipzig Aerosol Cloud Interaction Simulator (LACIS-mobile, RH = 98–99.3%). In addition, the cloud condensation nuclei (CCN) activity was measured applying two CCN counters (CCNC). An apparent single-hygroscopicity parameter, κ, of ∼0.09, ∼0.07–0.13, and ∼0.02–0.04 was derived from CCNC, HTDMA and LACIS data, respectively, assuming the surface tension of pure water. Closure between HTDMA and CCNC data was achieved within experimental uncertainty, whereas closure between LACIS and CCNC was only achieved by assuming a concentration-dependent surface tension reduction, consequently resulting in lower CCNC-derived κ values. Comparing different experimental techniques at varying precursor concentrations in more detail reveals further open questions. Varying precursor concentration influences hygroscopic growth factors at subsaturated RH, while it has no effect on the CCN activation. This difference in behaviour might be caused by precursor concentration-dependent surface tension depression or changing droplet solution concentration dependence of the water activity coefficient with varying SOA composition. Furthermore, evidence was found that the SOA might need several seconds to reach the equilibrium growth factor at high RH.
Schlagwörter
Fachgebiet (DDC)
550 - Geowissenschaften
Veranstaltung
Startdatum der Ausstellung
Enddatum der Ausstellung
Startdatum der Konferenz
Enddatum der Konferenz
Datum der letzten Prüfung
ISBN
ISSN
1463-9076
1463-9084
1463-9084
Sprache
Englisch
Während FHNW Zugehörigkeit erstellt
Nein
Publikationsstatus
Veröffentlicht
Begutachtung
Peer-Review der ganzen Publikation
Open Access-Status
Closed
Lizenz
Zitation
JURÁNYI, Zsófia, Martin GYSEL, Jonathan DUPLISSY, Ernest WEINGARTNER, Torsten TRITSCHER, Josef DOMMEN, Silvia HENNING, Markus ZIESE, Alexej KISELEV, Frank STRATMANN, Ingrid GEORGE und Urs BALTENSPERGER, 2009. Influence of gas-to-particle partitioning on the hygroscopic and droplet activation behaviour of α-pinene secondary organic aerosol. Physical Chemistry Chemical Physics. 5 August 2009. Bd. 11, Nr. 36, S. 8091–8097. DOI 10.1039/b904162a. Verfügbar unter: https://irf.fhnw.ch/handle/11654/46661