Development of a fluorophilic ion-exchange material with dual binding mechanism for solid-phase extraction of PFAS
Lade...
Autor:in (Körperschaft)
Publikationsdatum
11.2025
Typ der Arbeit
Studiengang
Sammlung
Typ
01A - Beitrag in wissenschaftlicher Zeitschrift
Herausgeber:innen
Herausgeber:in (Körperschaft)
Betreuer:in
Übergeordnetes Werk
Journal of Hazardous Materials Letters
Themenheft
DOI der Originalpublikation
Link
Reihe / Serie
Reihennummer
Jahrgang / Band
6
Ausgabe / Nummer
Seiten / Dauer
100158
Patentnummer
Verlag / Herausgebende Institution
Elsevier
Verlagsort / Veranstaltungsort
Auflage
Version
Programmiersprache
Abtretungsempfänger:in
Praxispartner:in/Auftraggeber:in
Zusammenfassung
Per- and polyfluoroalkyl substances (PFAS) are persistent contaminants for which authorities worldwide have imposed limits on drinking water, groundwater and surface water. This has created challenges in PFAS detection, leading to an urgent need for reliable and selective solid-phase extraction (SPE) materials for PFAS analysis. In addressing this demand, we have tailored highly crosslinked copolymers containing 3-(1H,1H,2H,2H-perfluorooctyl)-1-vinylimidazolium chloride as a comonomer with ethylene dimethacrylate in various molar ratios. For ionic fluorosurfactants, these copolymers feature a dual binding mechanism that synergistically combines fluorophilic interactions and electrostatic attraction, enhancing selectivity and efficiency. The adsorption behavior of short- and long-chain PFAS and their recoveries were evaluated and compared to commercial SPE cartridges. Characterization revealed the highest ion-exchange capacity (412.7 ± 22 µeq g−1) for a monomer-to-crosslinker ratio of 2:1. The dynamic adsorption capacities for various PFAS ranged from 15.2 to 306 g−1. Recovery experiments consistently demonstrated high PFAS recoveries (98.8–121.6 %), while enrichment studies from wastewater confirmed its robustness in complex environmental matrices (recoveries: 90.8–99.2 %). Additionally, reusability experiments showed consistent recoveries over five cycles (recoveries: 90.34–108.0 %). The findings underscore the potential of this innovative polyelectrolyte as a selective, regenerable, and efficient alternative to conventional SPE materials, qualifying it as a superior candidate for PFAS analysis.
Schlagwörter
PFAS, Solid-phase extraction, Fluorophilic polymer, Adsorption, Environmental analysis, Ion exchange
Fachgebiet (DDC)
Veranstaltung
Startdatum der Ausstellung
Enddatum der Ausstellung
Startdatum der Konferenz
Enddatum der Konferenz
Datum der letzten Prüfung
ISBN
ISSN
2666-9110
Sprache
Englisch
Während FHNW Zugehörigkeit erstellt
Ja
Zukunftsfelder FHNW
Zero Emission
Publikationsstatus
Veröffentlicht
Begutachtung
Peer-Review der ganzen Publikation
Open Access-Status
Gold
Lizenz
Zitation
Freilinger, J., Back, J. O., Plangger, R., Schottenberger, H., Huck, C. W., Rupprich, M., & Bakry, R. (2025). Development of a fluorophilic ion-exchange material with dual binding mechanism for solid-phase extraction of PFAS. Journal of Hazardous Materials Letters, 6, 100158. https://doi.org/10.1016/j.hazl.2025.100158