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Auflistung Hochschule für Technik FHNW nach Schlagwort "540 - Chemie"
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- PublikationCarbon mass determinations during the AIDA soot aerosol campaign 1999(Elsevier, 10/2003) Saathoff, Harald; Naumann, Karl-Heinz; Schnaiter, Martin; Schöck, Werner; Weingartner, Ernest; Baltensperger, Urs; Krämer, Lutz; Bozoki, Zoltan; Pöschl, Ulrich; Niessner, Reinhard; Schurath, Ulrich [in: Journal of Aerosol Science]During the soot aerosol campaign particle carbon mass concentrations of Diesel soot, spark generated “Palas” soot, external and internal mixtures of Diesel soot with (NH4)2SO4, and particles coated with secondary organic aerosol material were determined by several different methods. Two methods were based on thermochemical filter analysis with coulometric and NDIR detection of evolved CO2 (total carbon, TC and elemental carbon, EC) and four methods employed optical techniques: aethalometry (black carbon, BC), photoacoustic soot detection (BC), photoelectron emission, and extinction measurement at 473 nm. Furthermore, β-attenuation (total particulate mass), FTIR spectroscopy (sulphate), and COSIMA model calculations were used to determine particle mass concentrations. The general agreement between most methods was good although some methods did not reach their usual performance. TC determined by coulometric filter analysis showed good correlations with optical extinction, photoacoustic BC signal, and photoelectron emission data. However, the evolution of the photoelectron emission signal correlated with changes in accessible surface area rather than mass concentration and was very sensitive to surface conditions. The BC content as measured by the aethalometers approximately equal to less than 70% of the EC content for Diesel soot and amounts to less than 25% of the EC content of “Palas” soot.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationCharacterization of size-fractionated aerosol from the Jungfraujoch (3580 m asl) using total reflection x-ray fluorescence (TXRF)(Taylor & Francis, 22.09.2000) Streit, Niklaus; Weingartner, Ernest; Zellweger, Christoph; Schwikowski, Margit; Gäggeler, Heinz W.; Baltensperger, Urs [in: International Journal of Environmental Analytical Chemistry]During three field campaigns at the Jungfraujoch High Alpine Research Station, Switzerland, size-fractionated aerosol was collected using a cascade impactor. The particles were impacted on silicon oil-coated quartz sampling substrates. The actual analysis was then performed directly on these quartz sampling substrates using total reflection X-ray fluorescence. The resulting size distributions of 16 elements (S, Cl, K, Ca, Ti, Mn, Fe, Cu, Zn, Se, Br, Rb, Sr, Y, Zr, Pb) were investigated to determine the best cut-off diameter to distinguish between geogenic and anthropogenic particles. The obtained cut-off diameter of 1 μm is an important parameter in the current world-wide measurements under the auspices of the World Meteorological Organization's Global Atmosphere Watch aerosol project.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationHeterogeneous chemical processing of 13NO2 by monodisperse carbon aerosols at very low concentrations(American Chemical Society, 19.09.1996) Kalberer, Markus; Tabor, K.; Ammann, Markus; Parrat, Yves; Weingartner, Ernest; Piguet, D.; Rössler, E.; Jost, Dieter T.; Türler, Andreas; Gäggeler, Heinz W.; Baltensperger, Urs [in: The Journal of Physical Chemistry]The heterogeneous reaction of NO2 with different carbon aerosol particles was investigated in situ. The NO2 was labeled with the β+-emitter 13N (half-life 10.0 min) which allowed application of NO2 at very low concentrations. The carbon aerosol was either produced by a spark discharge generator using graphite electrodes or by a brush generator resuspending commercial soot material. Monodisperse size cuts between 50- and 490-nm diameter were selected and mixed with the 13NO2. After a defined reaction time, the different reaction products were separated by means of selective traps and detected on-line by γ-spectrometry. A sticking coefficient for chemisorption of NO2 between 0.3 × 10ˉ⁴ and 4.0 × 10ˉ⁴ and a rate constant for the reduction of adsorbed NO2 to NO(g) between 4.0 × 10 ˉ⁴ and 9.4 × 10 ˉ⁴ /s were determined for both aerosols. The sticking coefficient obtained in this study in situ with aerosol particles is 2 orders of magnitudes smaller than the uptake coefficient recently reported with bulk carbon material.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationHygroscopic properties of carbon and diesel soot particles(Elsevier, 08/1997) Weingartner, Ernest; Burtscher, Heinz; Baltensperger, Urs [in: Atmospheric Environment]Laboratory experiments were performed in order to study the hygroscopic properties of freshly produced carbon and diesel soot particles at subsaturations (i.e. at relative humidity < 100%). Wetted carbon aggregates collapsed to a more compact structure. In contrast, the diesel combustion particles exhibited a much smaller restructuring combined with condensational growth. The hygroscopicity of the diesel particles was enhanced when the sulfur content of the fuel was increased or when the particles were subjected to an ozone and UV pre-treatment. By extrapolating the data with a Köhler model critical supersaturations were calculated. Freshly emitted combustion particles are unlikely to act as cloud condensation nuclei whereas an aging of the particles will enhance their nucleation ability.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationProperties of jet engine combustion particles during the PartEmis experiment. Microphysics and Chemistry(Wiley, 15.07.2003) Petzold, Andreas; Stein, Claudia; Nyeki, Stephan; Gysel, Martin; Weingartner, Ernest; Baltensperger, Urs; Giebl, Heinrich; Hitzenberger, Regina; Döpelheuer, Andreas; Vrchoticky, Susi; Puxbaum, Hans; Johnson, M.; Hurley, Chris D.; Marsh, Richard; Wilson, Chris W. [in: Geophysical Research Letters]The particles emitted from an aircraft engine combustor were investigated in the European project PartEmis. Measured aerosol properties were mass and number concentration, size distribution, mixing state, thermal stability of internally mixed particles, hygroscopicity, and cloud condensation nuclei (CCN) activation potential. The combustor operation conditions corresponded to modern and older engine gas path temperatures at cruise altitude, with fuel sulphur contents (FSC) of 50, 410, and 1270 μg/g. Operation conditions and FSC showed only a weak influence on the microphysical aerosol properties, except for hygroscopic and CCN properties. Particles of size D ≥ 30 nm were almost entirely internally mixed. Particles of sizes D < 20 nm showed a considerable volume fraction of compounds that volatilise at 390 K (10–15%) and 573 K (4–10%), while respective fractions decreased to <5% for particles of size D ≥ 50 nm.01A - Beitrag in wissenschaftlicher Zeitschrift
- PublikationStudy on the chemical character of water soluble organic compounds in fine atmospheric aerosol at the Jungfraujoch(Springer, 07/2001) Krivácsy, Zoltán; Gelencsér, András; Kiss, Gyula; Mészáros, Ernő; Molnár, Ágnes; Hoffer, András; Mészáros, Tamás; Sárvári, Zsolt; Temesi, Dóra; Varga, Bálint; Baltensperger, Urs; Nyeki, Stephan; Weingartner, Ernest [in: Journal of Atmospheric Chemistry]In this study the chemical nature of the bulk of water soluble organic compounds in fine atmospheric aerosol collected during summer 1998 at the Jungfraujoch, Switzerland (3580 m asl) is characterised. The mass concentration of water soluble organic substances was similar to those of major inorganic ions, and the water soluble organic matter was found to be composed of two main fractions: (i) highly polyconjugated, acidic compounds with a varying degree of hydrophobicity and (ii) slightly polyconjugated, neutral and very hydrophilic compounds. The contribution of both fractions to the total water soluble organic carbon was about 50%. Separation into individual components was impossible either by HPLC or capillary electrophoresis which indicates the presence of a high number of chemically similar but not identical species. Results obtained by ultrafiltration and HPLC-MS have shown that the molecular weights are of the order of several hundreds. Most of the protonation constants for the acidic compounds determined by capillary electrophoresis were in the range 10⁴-10⁷.01A - Beitrag in wissenschaftlicher Zeitschrift